As per Rule if the principal manufacture is sending the excisable goods for Job work the material Movement details has to be maintained in Annexure - IV. In Tally.ERP 9 Annexure - IV can be generated when the Excise for Manufacturer feature is enable in F11: Features.
To view Annexure - IV
Go to Gateway of Tally > Display > Job Work Out Reports > Job Work Registers > Annexure - IV
The Annexure - IV is displayed as shown
For Column details refer the topic Material Movement Register